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21.
The Ombrone palaeovalley was incised during the last glacial sea‐level fall and was infilled during the subsequent Late‐glacial to Holocene transgression. A detailed sedimentological and stratigraphic study of two cores along the palaeovalley axis led to reconstruction of the post‐Last Glacial Maximum valley‐fill history. Stratigraphic correlations show remarkable similarity in the Late‐glacial to early‐Holocene succession, but discrepancy in the Holocene portion of the valley fill. Above the palaeovalley floor, about 60 m below sea‐level, Late‐glacial sedimentation is recorded by an unusually thick alluvial succession dated back to ca 18 cal kyr bp . The Holocene onset was followed by the retrogradational shift from alluvial to coastal facies. In seaward core OM1, the transition from inner to outer estuarine environments marks the maximum deepening of the system. By comparison, in landward core OM2, the emplacement of estuarine conditions was interrupted by renewed continental sedimentation. Swamp to lacustrine facies, stratigraphically equivalent to the fully estuarine facies of core OM1, represent the proximal expression of the maximum flooding zone. This succession reflects location in a confined segment of the valley, just landward of the confluence with a tributary valley. It is likely that sudden sediment input from the tributary produced a topographic threshold, damming the main valley course and isolating its landward segment from the sea. The seaward portion of the Ombrone palaeovalley presents the typical estuarine backfilling succession of allogenically controlled incised valleys. In contrast, in the landward portion of the system, local dynamics completely overwhelmed the sea‐level signal, following marine ingression. This study highlights the complexity of palaeovalley systems, where local morphologies, changes in catchment areas, drainage systems and tributary valleys may produce facies patterns significantly different from the general stratigraphic organization depicted by traditional sequence‐stratigraphic models.  相似文献   
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The thermal dehydration process of fibroferrite, FeOH(SO4)·5H2O, a secondary iron-bearing hydrous sulfate, was investigated by in situ high-temperature synchrotron X-ray powder diffraction (HT-XRPD), in situ high-temperature Fourier transform infrared spectroscopy (HT-FTIR) and thermal analysis (TGA-DTA) combined with evolved gas mass spectrometry. The data analysis allowed the determination of the stability fields and the reaction paths for this mineral as well as characterization of its high-temperature products. Five main endothermic peaks are observed in the DTA curve collected from room T up to 800 °C. Mass spectrometry of gases evolved during thermogravimetric analysis confirms that the first four mass loss steps are due to water emission, while the fifth is due to a dehydroxylation process; the final step is due to the decomposition of the remaining sulfate ion. The temperature behavior of the different phases occurring during the heating process was analyzed, and the induced structural changes are discussed. In particular, the crystal structure of a new phase, FeOH(SO4)·4H2O, appearing at about 80 °C due to release of one interstitial H2O molecule, was solved by ab initio real-space and reciprocal-space methods. This study contributes to further understanding of the dehydration mechanism and thermal stability of secondary sulfate minerals.  相似文献   
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The fine-scale heterogeneity of porous media affects the large-scale transport of solutes and contaminants in groundwater and it can be reproduced by means of several geostatistical simulation tools. However, including the available geological information in these tools is often cumbersome. A hierarchical simulation procedure based on a binary tree is proposed and tested on two real-world blocks of alluvial sediments, of a few cubic meters volume, that represent small-scale aquifer analogs. The procedure is implemented using the sequential indicator simulation, but it is so general that it can be adapted to various geostatistical simulation tools, improving their capability to incorporate geological information, i.e., the sedimentological and architectural characterization of heterogeneity. When compared with a standard sequential indicator approach on bi-dimensional simulations, in terms of proportions and connectivity indicators, the proposed procedure yields reliable results, closer to the reference observations. Different ensembles of three-dimensional simulations based on different hierarchical sequences are used to perform numerical experiments of conservative solute transport and to obtain ensembles of equivalent pore velocity and dispersion coefficient at the scale length of the blocks (meter). Their statistics are used to estimate the impact of the variability of the transport properties of the simulated blocks on contaminant transport modeled on bigger domains (hectometer). This is investigated with a one-dimensional transport modeling based on the Kolmogorov-Dmitriev theory of branching stochastic processes. Applying the proposed approach with diverse binary trees and different simulation settings provides a great flexibility, which is revealed by the differences in the breakthrough curves.  相似文献   
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International Journal of Earth Sciences - Our research is aimed at estimating the vertical deformation affecting late Quaternary units accumulated into the foreland basin of the Northern Apennines...  相似文献   
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Despite increased application of subsurface datasets below the limits of seismic resolution, reconstructing near‐surface deformation of shallow key stratigraphic markers beneath modern alluvial and coastal plains through sediment core analysis has received little attention. Highly resolved stratigraphy of Upper Pleistocene to Holocene (Marine Isotope Stage 5e to Marine Isotope Stage 1) alluvial, deltaic and coastal depositional systems across the southern Po Plain, down to 150 m depth, provides an unambiguous documentation on the deformation of previously flat‐lying strata that goes back in time beyond the limits of morphological, historical and palaeoseismic records. Five prominent key horizons, accurately selected on the basis of their sedimentological characteristics and typified for their fossil content, were used as highly effective stratigraphic markers (M1 to M5) that can be tracked for tens of kilometres across the basin. A facies‐controlled approach tied to a robust chronology (102 radiocarbon dates) reveals considerable deformation of laterally extensive nearshore (M1), continental (M2 and M3) and lagoon (M4 and M5) marker beds originally deposited in a horizontal position (M1, M4 and M5). The areas where antiformal geometries are best observed are remarkably coincident with the axes of buried ramp anticlines, across which new seismic images reveal substantially warped stratal geometries of Lower Pleistocene strata. The striking spatial coincidence of fold crests with the epicentres of historic and instrumental seismicity suggests that deformation of marker beds M1 to M5 might reflect, in part at least, syntectonically generated relief and, thus, active tectonism. Precise identification and lateral tracing of chronologically constrained stratigraphic markers in the 14C time window through combined sedimentological and palaeoecological data may delineate late Quaternary subsurface stratigraphic architecture at an unprecedented level of detail, outlining cryptic stratal geometries at the sub‐seismic scale. This approach is highly reproducible in tectonically active Quaternary depositional systems and can help to assess patterns of active deformation in the subsurface of modern alluvial and coastal plains worldwide.  相似文献   
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Back-analysis is broadly used for approaching geotechnical problems when monitoring data are available and information about the soils properties is of poor quality.For landslide stability assessment back-analysis calibration is usually carried out by time consuming trial-and-error procedure.This paper presents a new automatic Decision Support System that supports the selection of the soil parameters for three-dimensional models of landslides based on monitoring data.The method considering a pool of possible solutions,generated through permutation of soil parameters,selects the best ten configurations that are more congruent with the measured displacements.This reduces the operator biases while on the other hand allows the operator to control each step of the computation.The final selection of the preferred solution among the ten best-fitting solutions is carried out by an operator.The operator control is necessary as he may include in the final decision process all the qualitative elements that cannot be included in a qualitative analysis but nevertheless characterize a landslide dynamic as a whole epistemological subject,for example on the base of geomorphological evidence.A landslide located in Northeast Italy has been selected as example for showing the system potentiality.The proposed method is straightforward,scalable and robust and could be useful for researchers and practitioners.  相似文献   
30.
To better prioritise adaptation strategies to a changing climate that are currently being developed, there is a need for quantitative regional level assessments that are systematic and comparable across multiple weather hazards. This study presents an indicator-based impact assessment framework at NUTS-2 level for the European Union that quantifies potential regional changes in weather-related hazards: heat stress in relation to human health, river flood risk, and forest fire risk. This is done by comparing the current (baseline) situation with two future time periods, 2011–2040 and 2041–2070. The indicator values for the baseline period are validated against observed impact data. For each hazard, the method integrates outcomes of a set of coherent high-resolution regional climate models from the ENSEMBLES project based on the SRES A1B emission scenario, with current and projected non-climatic drivers of risk, such as land use and socio-economic change. An index of regional adaptive capacity has been developed and compared with overall hazard impact in order to identify the potentially most vulnerable regions in Europe. The results show strongest increases in impacts for heat stress, followed by forest fire risk, while for flood risk the sign and magnitude of change vary across regions. A major difference with previous studies is that heat stress risk could increase most in central Europe, which is due to the ageing population there. An overall assessment combining the three hazards shows a clear trend towards increasing impact from climaterelated natural hazards for most parts of Europe, but hotspot regions are found in eastern and southern Europe due to their low adaptive capacities. This spatially explicit assessment can serve as a basis for discussing climate adaptation mainstreaming, and priorities for regional development in the EU.  相似文献   
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